This paper gives the asymptotic theory of a class of rank order statistics $\{T_{N,j}, j=1\dots,c\}$ for $c$-sample problem pertaining to empirical processes based on the squared residuals from a class of ARCH models. An important aspect is that, unlike the residuals of ARMA models, the asymptotic distribution depends on those of ARCH volatility estimators. By an application of the asymptotic results, we propose the $c$-sample analogues of Mood's two-sample and Klotz's two-sample normal scores tests. These studies help to highlight some important features of ARCH residuals in comparison with the i.i.d. or ARMA settings.